Loading Events

Jeffrey I. Zink Inorganic Chemistry Seminar Series – Prof. Amanda Cook

Divisional Seminars, Inorganic

April 3, 2024 4:00 pm - 5:00 pm


Flyer: Prof. Amanda Cook Flyer

Title: Alkene Functionalization Using Homogeneous and Heterogeneous Catalysts

Abstract: Surface Organometallic Chemistry is an approach to synthesizing heterogeneous catalysts with molecular precision and relies on knowledge of homogeneous organometallic reactions. In our lab, we aim to install active sites on surfaces using oxidative addition of low-valent metal centers to surface functional groups. This strategy is a complementary route to the more common approaches (e.g., protonolysis of metal-ligand bonds by acidic surface sites) taken in surface organometallic chemistry. Using our approach, we developed a heterogeneous nickel-hydride catalyst that is highly active and selective for alkene isomerization. This reaction development was enabled by our work on homogeneous N-heterocyclic carbene-nickel catalysts for both alkene isomerization and hydrosilylation, which both utilize a nickel-hydride complex as the active catalyst.